ChemistryAngular momentumUniversity
Angular momentum magnitude commutator Calculator
Shows that any one angular-momentum component commutes with the total squared angular momentum.
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Formula first
Overview
This is why quantum states can be labeled by both l and one component quantum number m.
Apply it well
When To Use
When to use: Shows that any one angular-momentum component commutes with the total squared angular momentum.
Why it matters: This is why quantum states can be labeled by both l and one component quantum number m.
Avoid these traps
Common Mistakes
- Confusing this with the nonzero commutator between different components.
- Thinking all three components commute because each commutes with .
One free problem
Practice Problem
Can and Lz have simultaneous eigenfunctions?
Solve for: $[\hat{L}_i, \hat{L}^2]
Hint: Focus on what the formula is telling you physically.
The full worked solution stays in the interactive walkthrough.
References
Sources
- Chemistry LibreTexts, Rotational Motions of Rigid Molecules; Chemistry LibreTexts, Selection Rule for the Rigid Rotator
- Chemistry LibreTexts, Rotational Motions of Rigid Molecules
- Chemistry LibreTexts, Selection Rule for the Rigid Rotator
- Griffiths, David J. (2018). Introduction to Quantum Mechanics (3rd ed.). Cambridge University Press.
- Sakurai, J. J., & Napolitano, Jim. (2017). Modern Quantum Mechanics (2nd ed.). Cambridge University Press.
- Griffiths, David J. Introduction to Quantum Mechanics
- Sakurai, J. J., & Napolitano, J. Modern Quantum Mechanics